东华大学学报(英文版)

2020, v.37(02) 116-120

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Existence Criterion of Three-Dimensional Regular Copper-1,3,5-Phenyltricarboxylate (Cu-BTC) Microparticles
Existence Criterion of Three-Dimensional Regular Copper-1,3,5-Phenyltricarboxylate (Cu-BTC) Microparticles

杨成飞;高东杰;何吉欢;

摘要(Abstract):

Nano or micro-scale particles are considered as a zero-dimensional material, and their shape is difficult to control. Here the crystal-like microparticles are formed, and the existence criterion of crystal-like low dimensional materials is established. The hydrothermal method is used to fabricate copper-1,3,5-phenyltricarboxylate(Cu-BTC) microparticles, which have a regular geometric shape with regular triangle, quadrangle and hexagon. The benzene ring and carboxyls(—COOH) attached to the benzene ring form two basic molecular structures of [Cu_3(BTC)_2]_n, which play an essential role in the construction of a three-dimensional crystal-like structure.

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基金项目(Foundation): National Natural Science Foundation of China(No.11372205)

作者(Author): 杨成飞;高东杰;何吉欢;

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